logo
search
Send & Receive Issues

Fix Cannot Send Email from an Alias in Outlook on the Web

Bushra ParveenBushra Parveen Oct 12, 2026 868 views

Question details

The user is unable to send emails using an Exchange Online alias via Outlook on the web, even though the same alias works fine in the Outlook desktop application.

How to Fix Cannot Send Email from an Alias in Outlook on the Web
Product
Outlook on the Web
Device & OS
not provided
Scenario
Attempting to compose and send an outgoing message using a configured email alias via the web version of Outlook.
Observed behavior
The email fails to send because the alias is not properly enabled in the web settings, or a cached and incorrect autocomplete address is being used.
Before you start

Ensure that your Microsoft 365 administrator has correctly added the alias to your Exchange Online account and allowed sufficient time (up to 24 hours) for the server changes to propagate.

Solution 1Recommended

Enable the Alias in Compose and Reply Settings

Outlook on the web requires you to manually select which aliases you are permitted to send from before they can be used in the 'From' field.

By default, newly added aliases might not be visible in your sending options on the web until they are explicitly enabled in the settings menu.

1
Open Outlook Settings

Log in to Outlook on the web and click the Settings (gear) icon in the top right corner of the screen.

2
Navigate to Compose and Reply

Go to 'Mail' in the left sidebar, then select 'Compose and reply'.

3
Select Addresses to Send From

Scroll down to the 'Addresses to send from' section and check the box next to the alias you want to use.

4
Save Changes

Save your settings. You should now be able to select this alias from the 'From' dropdown when composing a new message.

Enable the Alias in Compose and Reply Settings
Alias Enabled: Once enabled, the alias will appear as a selectable option every time you compose a new email or reply to a message.
Free Microsoft Office alternative

Looking for a Lightweight Office Suite? Try WPS Office

While resolving your Microsoft Outlook web issues, consider equipping your device with a fast, free, and highly compatible office suite for your document needs. WPS Office provides an intuitive, all-in-one platform for Word, Excel, PowerPoint, and PDF files without heavy subscription fees.

Fully compatible with Microsoft Office formats (.docx, .xlsx, .pptx).Lightweight installation that runs smoothly on older devices.Familiar, tabbed user interface for seamless migration.Built-in robust PDF editing and conversion tools.
microsoft office alternative - wps office

Frequently Asked Questions

Why does my email alias work in the Outlook desktop app but not on the web?

Outlook on the web often requires you to manually select which aliases are allowed for sending within its specific settings menu (Mail > Compose and reply). The desktop client syncs and handles these permissions differently directly from Exchange.

How long does it take for a newly created alias to show up in Outlook on the web?

It can take up to 24 hours for a new Exchange Online alias to fully sync across Microsoft 365 servers and become available in your Outlook on the web settings.

Can I make my alias the default sending address in Outlook on the web?

Yes. You can set the default 'From' address by going to Settings > Mail > Compose and reply, and selecting your preferred alias under the 'Set default From address' dropdown menu.